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HOMEBREW Digest #2650
HOMEBREW Digest #2650 Mon 02 March 1998
FORUM ON BEER, HOMEBREWING, AND RELATED ISSUES
Digest Janitor: janitor@hbd.org
Many thanks to the Observer & Eccentric Newspapers of
Livonia, Michigan for sponsoring the Homebrew Digest.
URL: http://www.oeonline.com
Contents:
RE: Salt additions / hazy beer (George_De_Piro)
Private reply by Wolfgang Kunze (fwd) re: FWH and chill haze (Tidmarsh Major)
More Water-Treatment Questions (KennyEddy)
Salts addition, ("David R. Burley")
BT Authors ("David R. Burley")
Re: Worried or Not? Mead question.... (Charles Burke)
Re: European swallows/US pints ("John C. Tull")
Beer history (David Kerr)
Spalt rhizomes (Matthew Arnold)
Steinbier (George_De_Piro)
Devine Brew ("Frederick J. Wills")
Attention Central PA residents! (Jonathan Ingram)
Large 29 mm caps (Edward J. Basgall)
Re: European swallows/US pints ("John C. Tull")
Irish Moss (Al Korzonas)
water chemistry, ppm (JKW)
chloramines and filters (James Tomlinson)
1 BBL RIMS Design (Kyle Druey)
Correction (AJ)
Colour units (Al Korzonas)
re:1 bbl RIMS (Brad Johnson)
Making Rootbeer (Bill_Rehm)
RE: Long Secondaries/Spent Grain Dog Bones (LaBorde, Ronald)
Metric system/pint/1984 ("Michael Maag")
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----------------------------------------------------------------------
Date: Thu, 26 Feb 1998 08:24:09 -0800
From: George_De_Piro@berlex.com
Subject: RE: Salt additions / hazy beer
Hi all,
Kyle asks some good questions about salt additions. He wonders if
they are used primarily for flavor effects or pH control of the mash.
He also wonders when to add them, and how much.
Salt additions can be used for both pH control and flavor effects.
The problems with using them for pH control are:
1. You will also get the flavor effects, which may be undesirable.
2. It's not Reinheitsgebot (not a problem for some).
3. By adding salts, you will increase the concentrations of some ions
that you need, but you will also increase the concentration of ions
you may not want.
For example, if you add gypsum (calcium sulphate, CaSO4) to the mash
to increase Ca+2 (to lower mash pH), you will also be increasing the
SO4-2 ion. SO4 has a pretty large effect on the flavor of the beer
(increases and alters the perception of hop bitterness). If you are
brewing a Muenchner Helles this is not desirable!
If you are using salts to control mash pH, obviously they must be
added to the mash. It is easiest to add them to the water before
mash in (to ensure even distribution). Of course, some salts are not
very soluble in plain water (like calcium carbonate), but most people
don't have a need to add this. If you must add this, it will dissolve
in the mash (weakly acidic solution).
You *absolutely* must know your water's natural chemistry before you
start throwing all sorts of salts into your brewing water! I cannot
stress this enough! Recipes that blindly call for salt additions
should ignored!!!
Think about it this way: you decide to use calcium chloride (CaCl2)
to lower your mash pH. Your brewing water may already be near the
upper limit for desirable chloride content. By adding more, you just
pushed it way over the top. The same is true for all the ions you
might add.
If you are adding salts simply for their flavor contribution, you can
add them to the boil rather than the mash. You should have a decent
gram scale for weighing out salts. Volume measurements really don't
cut it. The amounts you add are dependent on your water's natural
chemistry.
----------------------------
There has been some talk about hazy beer. I used to think, "What the
heck, a little haze is natural." This is true for some styles. Haze
can signify other problems, though.
Haze can simply be "chill haze," a protein-phenol complex that becomes
insoluble at cold temperatures and thus clouds your cool brew. Haze
can also be caused by excessive starch. Starch in beer is bad. It
shows that there are fundamental problems with your techniques, and
leads to beer stability and flavor problems.
Haze can also be caused by yeast that have not flocculated. Most
brewing yeasts usually flocculate, so lack of flocculation can be the
sign of some problems. Wild yeasts tend to not flocculate. You don't
want them in your beer (for several reasons)! Suspended yeast can
make the beer taste yeasty, too. As Jim Busch pointed out, this is
not often desirable.
Haze can also be caused by an extreme bacterial infection. If your
beer is turbid from bacteria you will probably be put off by its
aroma before the appearance can ever bother you, though.
So, as you can see, haze is not always the innocuous creature that
many believe it to be. It is relatively easy to produce clear beer
without filtration in a homebrewery. If you don't like haze, there is
no reason to tolerate it!
Have fun!
George De Piro (Nyack, NY)
------------------------------
Date: Thu, 26 Feb 1998 09:59:12 -0500 (EST)
From: Tidmarsh Major <tmajor@parallel.park.uga.edu>
Subject: Private reply by Wolfgang Kunze (fwd) re: FWH and chill haze
Hubert Hanghofer passed the following reply from Wolfgang Kunze to me to
forward to the list. Between the two of us, I think we've made a
reasonable translation of the German reply (which I include for those who
can understand it better than I).
Tidmarsh Major
tmajor@parallel.park.uga.edu
- ---------- Forwarded message from Hubert Hanghofer, edited by me --------
To conclude, the context is clear to me
- in my humble English:
He's very pleased that we have such a great forum. Unfortunately his
English is not very good, so he prefers to mail in German.
( -Note that I've read that the book was translated by an English
Author )
Hop polyphenols have a significantly higher degree of condensation
[coagulation, perhaps?] and a higher reactivity than malt
polyphenols. The latter [malt polyphenols] count for 80% of the
polyphenols in wort. If hops are added at beginning, the hop polyphenols
react quickly, whereas a higher part of the slow reacting malt polyphenols
remain in the wort and in the final beer, where they -because of low
reactivity- cause haze in a later stage. That's the main reason for point
11.
CHEERS &
sehr zum Wohle!
Hubert
- ------- Forwarded Message Follows -------
Date: Wed, 25 Feb 98 15:46 +0100
To: hhanghof@netbeer.co.at
From: (Wolfgang Kunze)
Sehr geehrter Herr Hanghofer,
Ihr interessantes e-mail wurde mir von Herrn Hendel von unserer VLB
uebermittelt, erreichte mich aber wegen eines Urlaubs erst jetzt. Ich
freue mich, dass die die Haus- und Microbrewer so intensiv und
kompetent ueber eine elektronische mailingliste miteinander
kommunizieren und sich auch wirklich ernsthaft mit den vielen Fragen
und Problemen bei der Bierherstellung auseinanderzusetzen. Leider ist
mein Englisch etwas mangelhaft, so dass ich mich lieber in der
deutschen Sprache an Sie wende. Ich bitte Sie aber, den so
Interessierten Haus- und Mikrobrauern auf diesem Wege meine Freude
darueber zum Ausdruck zu bringen. Wenn ich nun die Diskussion richtig
verstehe, geht es um die Frage, wie der Punkt 11 auf S.396 deutsch =
242 englisch:
- Hopfengabe nicht zu frueh - Malzgerbstoffe sollen reagieren
zu bewerten sei.
Diese alte Erkenntnis beruht darauf, dass die Polyphenole des Hopfens
in einem wesentlich hheren Kondensationsgrad vorliegen und auch
wesentlich reaktionsfreudiger sind als die Polyphenole aus dem Malz,
die aber wiederum etwa 80% der gesamten Polyphenole in der Wrze
ausmachen. Wird der Hopfen am Anfang zugesetzt, reagieren seine
Gerbstoffe sehr rasch, whrend die langsam reagierenden aus dem Malz
zu einem hheren Anteil in der Wuerze und im Bier verbleiben und bei
ihrer Reaktionstrgheit erst viel spaeter zu einer Truebung im Bier
Anlass geben. Das ist die Hauptursache dieser Aussage, die natuerlich
bei Verwendung von PVPP oder anderen Adsorbentien nicht mehr so zum
Tragen kommt. Ich weiss allerdings nicht, ob die Microbrewer
Adsorbentien oder Faellungsmittel zur Stabilisierung verwenden. Ich
hoffe, dass Ihnen diese Aussage genuegt und bin gern bereit, bei
weiteren Fragen Rede und Antwort zu stehen (aber moeglichst in
deutsch).
Mit freundlichen Gruessen
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Ing. Hubert Hanghofer
Maxstrasse 21 Privat +43-662-87 82 13
A-5020 Salzburg Bro +43-6245-890 442
- --
DIE HAUSBRAUEREI
vom Einstieg zur Braukunst
Infos unter
http://www.netbeer.co.at/beer/
------------------------------
Date: Thu, 26 Feb 1998 10:05:28 EST
From: KennyEddy@aol.com
Subject: More Water-Treatment Questions
Kyle Druey writes:
I have a few questins while we are on the topic of water chemistry and
salt addition.
1) When do you add salt additions: to the gross brewing water volume
(this is the final beer volume plus extra water to account for any
losses in the brewing process), to the mash tun, to the boil kettle?
I add everything to the "gross brewing water" volume, though I don't think my
brewing water is all *that* gross ;-). I buy my RO water in two 5-gallon
plastic carboys (with handles), measure in the salts, and pick the bastards up
and shake them (it's actually pretty easy with the handles). That said, there
are special cases where adding to the mash is appropriate; see below.
2) If you add salts to the gross brewing water volume some salts will
not readily dissolve until lactic acid is added. Is this normal, or am
I doing something wrong?
"Some slats" is probably chalk. This will only dissolve at a rate of about
1/4 gram per 5 gallons! This amount of chalk is not enough to significantly
affect the ion composition, so chalk additions to plain unacidified water is
useless. The other salts that I use -- epsom salts, baking soda, non-iodized
table salt, calcium chloride, and gypsum -- dissolve quite readily in water.
The addition of acid will improve the dissolution of chalk. AJ deLange has
proposed bubbling CO2 though the water to lower its pH (by creation of
carbonic acid, BTW this mimics natural processes) and facilitate chalk
dissolution.
3) Are the salts added primarily to pre-adjust the mash pH, or for
flavor effects in the finished beer? Seems as if the types/amounts of
salts needed would then be a function of what your objectives are. If
you just want to alter mash pH, then the famous brewing water profiles
commonly found in homebrewing texts may not be very useful.
This post was made before my response to Scott Murman in a recent HBD. Go
back a couple issues and look for it if you didn't catch it. Bottom line --
you're right, but as always, It Depends.
4) I have been calculating my salt additions based on the gross water
volume, and adding them there. Like I mentioned above, some salts do
not readily dissolve, but I add this water to the mash tun anyway. The
remainder of the water is used for sparging, which is acidified with
lactic acid, after which the mineral salts dissolve. What happens to the
undissolved salts that are added to dough in the grist? Do they
dissolve once the mash pH is adjusted, or do they somehow get 'trapped'
in the grain bed?
You can work with undissolved chalk if you can keep it suspended (by vigorous
stirring) during strike-in. This will ensure it's evenly distributed and it
will dissolve once it reacts with the malt. Adding to the mash after mash-in
will work too since the acidity of the mash will dissolve the chalk readily.
Note that chalk is calcium carbonate. The calcium wants to react with the
mash to lower pH (by creating acid); but the carbonate wants to add alkalinity
and raise pH. In this race, the carbonate wins after a certain amount of
chalk. So watch your mash pH if you add chalk.
5) Once you add the salts, and you then have to add more salts to
adjust the mash pH, what happens then? Do you run the risk of adding
too much of the wrong kinds of minerals?
Gypsum (calcium sulphate) is a common mash acidifier, and adding more gypsum
adds more sulphate which can be detrimental to some styles. For these kinds
of beers, adding acid may be a better choice to avoid sulphate.
6) Are calculating salt additions worth the time and effort? Or is it
just easier, and produces the same outcome, to ignore salt
additions/calculations and adjust the mash pH with lactic acid to lower
the pH, and use calcium carbonate to increase the pH?
Mash pH should always be the last word in your salt additions, but creating
"profiles" for specific flavor effects is also one of the goals. In my recent
post I suggested a few simple recipes that should cover most of your brewing
situations, if you don't want to do the work yourself (or if you just want a
"good-enough" water). I doubt that subtle "errors" versus published "classic"
water profiles will have any discernable effect on your beer.
I am sure most of us have read that the Bavarians originally could not
brew Pilsners because when they mashed with lightly kilned malts and
added their hard water (hard when compared to Pilzen) to the grist the
resulting mash pH was not enzyme friendly. Perhaps designing mineral
salt recipes based on the composition of the grist is more appropiate?
i.e. darker malts generally lower the mash pH, design water recipes the
account for this... Doesn't Daniels in his book DGB suggest that the
mash pH will be lowered by 0.2 for every 10% of dark malts that comprise
the grist?
I have seen a couple of sources on figuring mash pH vs composition but in my
ignorance I'm guessing it's much more complicated than simply plugging in a
grain bill and water chemistry and getting an accurate pH (but who knows).
I've read (Daniels? Pappazian?) that adding distilled water to pale malt will
establish a pH around 5.9 (or thereabouts), too high for proper efficient
enzyme action. Adding calcium facilitates creation of pH-reducing acid.
Adding acid lowers pH. Letting the grist "go lactic" biologically will lower
the pH. Adding dark malts will lower pH.
*****
Ken Schwartz
El Paso, TX
KennyEddy@aol.com
http://members.aol.com/kennyeddy
------------------------------
Date: Thu, 26 Feb 1998 10:16:56 -0500
From: "David R. Burley" <Dave_Burley@compuserve.com>
Subject: Salts addition,
Brewsters:
Kyle Druey asks about when and how much minerals to add
to produce beer.
The Ca ion content in pale ale malt mashes should be around
50 ppm in the mash to provide the correct pH and avoid interfering
with enzyme activity. In the case of Pilsners and RO water, I
don't add any minerals at any time and it all works fine. If you
choose to do the real Burton style waters add half of the salts
in the mash tun and the other half in the sparge and avoid adding
lactic acid if you are searching for real ale authenticity.
To get the calcium carbonate to dissolve you may have to treat
a sample of water and salts with CO2 using a carbonater and
a liter soda bottle.
Your idea of using the grist composition to determine the
mineralization of the brewing liquor is, of course, just the
opposite of the early brewers who varied the grist to match
the local water. This resulted in beers which were distinctive
by geography.
- -----------------------------------------------------------
Keep on brewin'
Dave Burley
Kinnelon, NJ 07405
103164.3202@compuserve.com
Dave_Burley@compuserve.com
Voice e-mail OK
------------------------------
Date: Thu, 26 Feb 1998 10:42:51 -0500
From: "David R. Burley" <Dave_Burley@compuserve.com>
Subject: BT Authors
Brewsters:
Wow!! was I impressed to read the list of authors in the
January/February Brewing Techniques; HBD swept the issue!
Louis Bonham with Andy Thomas, Dion Hollenbeck and
Spencer Thomas were the authors familiar to us all and
Al Korzonas' letter to Dave Miller had Miller explaining and
apologizing page after page. Well Done!!
For those who are BT impaired call 541-687-2993 or
e-address is circulation@brewtech.com
No affiliation, yadda.
Keep on brewin'
Dave Burley
Kinnelon, NJ 07405
103164.3202@compuserve.com
Dave_Burley@compuserve.com
Voice e-mail OK
------------------------------
Date: Thu, 26 Feb 1998 09:03:00 -0700 (MST)
From: Charles Burke <charles@pluto.ame.arizona.edu>
Subject: Re: Worried or Not? Mead question....
Michael Tucker (mrtucker@fayettevillenc.com) wrote:
> OK- so far so good. the book suggests that you rack the mead
> off of the sediment once a month or so. OK- fine. I sanitized
> another carboy, racked the mead off of the sediment, topped it
> back off with a gallon or so of clean, sanitary spring water
> (also suggested by the book), repositioned my ferm lock, and
> nada. Nothing. no visible signs of life. No glubs from the
> ferm lock, nothing. the mead is clear, I can see through the
> stuff- a dark reddish golden color. I did taste it- I was
> disappointed in the flavor, but it didn't taste "sour" or "off"
> like it had been contaminated.... I figure it was still "raw"
> and needs time to mellow. I guess what has me worried is that
> moments before I racked it, it was bubbling away- one glub
> every 3 minutes of so. Moments after the transfer, nada. Its
> almost like i wiped out the wee beastie yeasties in toto. I
> can't believe that to be true- but that's what its like.
Greetings, Michael (et al...) -
Remember that you had a slow fermentation rate of "0.3 glub/min"
and that racking drives A LOT of CO2 out of solution. I suspect
that your fermentation IS active, but the CO2 is just going
directly into solution rather than escaping. It seems reasonable
to suppose that no gas will come out until the dissolved CO2
concentration reaches saturation. That could take a while given
the CO2 production rate you gave.
Your batch sounds just like the plain 3# mead that I started back
in Spring '93. I had the same experience when I racked the
stuff. It had a comparable fermentation rate as yours at the
time. The airlock did start bubbling again after "a few" days (I
can't remember exactly how long it took).
As for the rest - Yes, the must wouldn't taste terrific at this
point. Mine took 2 years after bottling to even start to mellow,
and about 15 months to ferment out completely (FG = 0.997 IIRC).
This was also with champagne yeast and a "cautious" dose of
nutrient. Take heart, though - the final product should be
fantastic. Mine has finally taken of the characteristic of a
good white wine. Mostly like a chardonnay, but with a completely
different aftertaste.
Unfortunately, much patience is required of the meadmaker...
- Charlie
- ---------------------------------------------
Charles R. Burke, Research Assistant
University of Arizona
Bldg. 119
Dept. of Aerospace and Mechanical Engineering
1130 N Mountain Ave.
Tucson AZ 85721
charles@cfd.ame.arizona.edu
(520)621-4369 work, (520)621-8191 fax
------------------------------
Date: Thu, 26 Feb 1998 08:31:18 -0800
From: "John C. Tull" <jctull@unr.edu>
Subject: Re: European swallows/US pints
>Here in the States we're getting ripped off and no one is saying a
word.
>When I ask for a pint, I want A PINT. What we usually get is a 12oz
pour
>in an American "pint" glass. A glass of beer is usually about 8oz.
>
>I really wish publicans would get their act together and serve a REAL
>pint when asked for.